Observation of Fe−H/D Modes by Nuclear Resonant Vibrational Spectroscopy
نویسندگان
چکیده
منابع مشابه
Observation of Fe-H/D modes by nuclear resonant vibrational spectroscopy.
Metal-hydrogen bonding is important in chemistry and catalysis, but H atoms are often difficult to observe, especially in metalloproteins. In this work we show that Fe-H interactions can be probed by nuclear resonance vibrational spectroscopy at the 14.4 keV 57Fe nuclear resonance. An important advantage of this method, compared to Raman and IR spectroscopy, is the selectivity for modes that in...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2003
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja028767+